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The sluggish kinetics of the oxygen evolution reaction (OER) is the bottleneck for the practical exploitation of water splitting. Here, the potential of a core–shell structure of hydrous NiMoO4 microrods conformally covered by Co3O4 nanoparticles via atomic layer depositions is demonstrated. In situ Raman and synchrotron‐based photoemission spectroscopy analysis confirms the leaching out of Mo facilitates the catalyst reconstruction, and it is one of the centers of active sites responsible for higher catalytic activity. Post OER characterization indicates that the leaching of Mo from the crystal structure, induces the surface of the catalyst to become porous and rougher, hence facilitating the penetration of the electrolyte. The presence of Co3O4 improves the onset potential of the hydrated catalyst due to its higher conductivity, confirmed by the shift in the Fermi level of the heterostructure. In particular NiMoO4@Co3O4 …
Publication date: 
1 Aug 2021

Getachew Solomon, Anton Landström, Raffaello Mazzaro, Matteo Jugovac, Paolo Moras, Elti Cattaruzza, Vittorio Morandi, Isabella Concina, Alberto Vomiero

Biblio References: 
Volume: 11 Issue: 32 Pages: 2101324
Advanced Energy Materials